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Accessibility information
Author(s):   Tomas, A.; Villenave, E.; Lesclaux, R.
Title:   Kinetics of the (CH3)2CHCO and (CH3)3CCO Radical Decomposition: Temperature and Pressure Dependences
Journal:   Phys. Chem. Chem. Phys.
Volume:   2
Page(s):   1165 - 1174
Year:   2000
Reference type:   Journal article
Squib:   2000TOM/VIL1165-1174

Reaction:   (CH3)2CHC=O → Propyl Radical + CO
Reaction order:   1
Temperature:   403 - 503 K
Rate expression:   3.3x1014 [s-1] e-59407 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
403 6.59E6
425 1.65E7
450 4.20E7
475 9.68E7
500 2.05E8
503 2.24E8