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Accessibility information
Author(s):   Tomas, A.; Villenave, E.; Lesclaux, R.
Title:   Kinetics of the (CH3)2CHCO and (CH3)3CCO Radical Decomposition: Temperature and Pressure Dependences
Journal:   Phys. Chem. Chem. Phys.
Volume:   2
Page(s):   1165 - 1174
Year:   2000
Reference type:   Journal article
Squib:   2000TOM/VIL1165-1174

Reaction:   (CH3)3CC(O)· → Products + CO
Reaction order:   1
Temperature:   323 - 453 K
Rate expression:   1.1x1014 [s-1] e-50635 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
323 7.13E5
325 8.01E5
350 3.05E6
375 9.74E6
400 2.69E7
425 6.58E7
450 1.46E8
453 1.60E8