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Accessibility information
Author(s):   Zhang, Y.-X.; Bauer, S.H.
Title:   Gas-Phase Pyrolyses of 2-Nitropropane and 2-Nitropropanol: Shock-Tube Kinetics
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   1207 - 1216
Year:   2000
Reference type:   Journal article
Squib:   2000ZHA/BAU1207-1216

Reaction:   2-nitropropaneiso-C3H7 + NO2
Reaction order:   1
Temperature:   970 - 1150 K
Pressure:  4.56 - 6.08 bar
Rate expression:   3.5x1014 [±1.2x1014 s-1] e-226773 [±15899 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In both real time and by end product analysis
Analytical technique:   Vis-UV absorption
Comments:   The unimolecular rate constant deduced from the loss of 2-nitropropane at the high-pressure limit

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
970 2.15E2
975 2.48E2
1000 5.00E2
1025 9.72E2
1050 1.83E3
1075 3.35E3
1100 5.97E3
1125 1.04E4
1150 1.75E4