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Author(s):   Bedjanian, Y.; Riffault, V.; Poulet, G.
Title:   Kinetic Study of the Reactions of BrO Radicals with HO2 and DO2
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   3167 - 3175
Year:   2001
Reference type:   Journal article
Squib:   2001BED/RIF3167-3175

Reaction:   HO2 + BrOO3 + HBr
Reaction order:   2
Reference reaction:   HO2 + BrO → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.33E-3 bar
Rate expression:   4.0x10-3
Rate constant is an upper limit.
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   BrO radicals were produced from; O2 (microwave discharge) -> 2O; O+Br2->BrO+Br or Br+O3->BrO+O2.

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