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Accessibility information
Author(s):   D'Anna, B.; Andresen, O.; Gefen, Z.; Nielsen, C.J.
Title:   Kinetic Study of OH and NO3 Radical Reactions with 14 Aliphatic Aldehydes
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   3057 - 3063
Year:   2001
Reference type:   Journal article
Squib:   2001DAN/AND3057-3063

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2001DAN/AND3057-3063   CH3CHO + NO3 → Products  298   0.19           0.19  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   CH3CHO + NO3 → Products  298   2.60E-15           2.60E-15  2
  2001DAN/AND3057-3063   C2H5CHO + NO3 → Products  298   0.65           0.65  2
  Reference reaction:  CH3CH=CH2 + NO3 → Products 2
  2001DAN/AND3057-3063   C2H5CHO + NO3 → Products  298   6.20E-15           6.20E-15  2
  2001DAN/AND3057-3063   CH3CH2CH2CHO + NO3 → Products  298   0.91           0.91  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   CH3CH2CH2CHO + NO3 → Products  298   1.22E-14           1.22E-14  2
  2001DAN/AND3057-3063   (CH3)2CHCHO + NO3 → Products  298   0.93           0.93  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   (CH3)2CHCHO + NO3 → Products  298   1.26E-14           1.26E-14  2
  2001DAN/AND3057-3063   n-C4H9CHO + NO3 → Products  298   1.27           1.27  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   n-C4H9CHO + NO3 → Products  298   1.71E-14           1.71E-14  2
  2001DAN/AND3057-3063   sec-C4H9CHO + NO3 → Products  298   1.98           1.98  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   sec-C4H9CHO + NO3 → Products  298   2.68E-14           2.68E-14  2
  2001DAN/AND3057-3063   3-Methylbutanal + NO3 → Products  298   1.38           1.38  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   3-Methylbutanal + NO3 → Products  298   1.86E-14           1.86E-14  2
  2001DAN/AND3057-3063   2,2-dimethylpropanal + NO3 → Products  298   1.92           1.92  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   2,2-dimethylpropanal + NO3 → Products  298   2.59E-14           2.59E-14  2
  2001DAN/AND3057-3063   n-C5H11CHO + NO3 → Products  298   1.14           1.14  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   n-C5H11CHO + NO3 → Products  298   1.14E-14           1.14E-14  2
  2001DAN/AND3057-3063   n-C3H7CH(CH3)CHO + NO3 → Products  298   1.99           1.99  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   n-C3H7CH(CH3)CHO + NO3 → Products  298   2.69E-14           2.69E-14  2
  2001DAN/AND3057-3063   NO3 + C2H5CH(CH3)CH2CHO → Products  298   1.78           1.78  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   NO3 + C2H5CH(CH3)CH2CHO → Products  298   2.41E-14           2.41E-14  2
  2001DAN/AND3057-3063   CH3CH(CH3)C2H4CHO + NO3 → Products  298   1.25           1.25  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   CH3CH(CH3)C2H4CHO + NO3 → Products  298   1.68E-14           1.68E-14  2
  2001DAN/AND3057-3063   neo-C5H11CHO + NO3 → Products  298   1.27           1.27  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   neo-C5H11CHO + NO3 → Products  298   1.71E-14           1.71E-14  2
  2001DAN/AND3057-3063   (C2H5)2CHCHO + NO3 → Products  298   3.31           3.31  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  2001DAN/AND3057-3063   (C2H5)2CHCHO + NO3 → Products  298   3.31E-14           3.31E-14  2
  2001DAN/AND3057-3063   CH3CHO + ·OH → Products  298   0.46           0.46  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   CH3CHO + ·OH → Products  298   1.44E-11           1.44E-11  2
  2001DAN/AND3057-3063   C2H5CHO + ·OH → Products  298   0.72           0.72  2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  2001DAN/AND3057-3063   C2H5CHO + ·OH → Products  298   1.90E-11           1.90E-11  2
  2001DAN/AND3057-3063   CH3CH2CH2CHO + ·OH → Products  298   0.76           0.76  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   CH3CH2CH2CHO + ·OH → Products  298   2.38E-11           2.38E-11  2
  2001DAN/AND3057-3063   (CH3)2CHCHO + ·OH → Products  298   0.85           0.85  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   (CH3)2CHCHO + ·OH → Products  298   2.65E-11           2.65E-11  2
  2001DAN/AND3057-3063   n-C4H9CHO + ·OH → Products  298   0.83           0.83  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   n-C4H9CHO + ·OH → Products  298   2.61E-11           2.61E-11  2
  2001DAN/AND3057-3063   sec-C4H9CHO + ·OH → Products  298   1.04           1.04  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   sec-C4H9CHO + ·OH → Products  298   3.28E-11           3.28E-11  2
  2001DAN/AND3057-3063   3-Methylbutanal + ·OH → Products  298   0.89           0.89  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   3-Methylbutanal + ·OH → Products  298   2.79E-11           2.79E-11  2
  2001DAN/AND3057-3063   2,2-dimethylpropanal + ·OH → Products  298   0.85           0.85  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   2,2-dimethylpropanal + ·OH → Products  298   2.68E-11           2.68E-11  2
  2001DAN/AND3057-3063   n-C5H11CHO + ·OH → Products  298   0.91           0.91  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   n-C5H11CHO + ·OH → Products  298   2.86E-11           2.86E-11  2
  2001DAN/AND3057-3063   n-C3H7CH(CH3)CHO + ·OH → Products  298   1.06           1.06  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   n-C3H7CH(CH3)CHO + ·OH → Products  298   3.32E-11           3.32E-11  2
  2001DAN/AND3057-3063   ·OH + C2H5CH(CH3)CH2CHO → Products  298   0.93           0.93  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   ·OH + C2H5CH(CH3)CH2CHO → Products  298   2.91E-11           2.91E-11  2
  2001DAN/AND3057-3063   CH3CH(CH3)C2H4CHO + ·OH → Products  298   0.84           0.84  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   CH3CH(CH3)C2H4CHO + ·OH → Products  298   2.63E-11           2.63E-11  2
  2001DAN/AND3057-3063   neo-C5H11CHO + ·OH → Products  298   0.68           0.68  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   neo-C5H11CHO + ·OH → Products  298   2.14E-11           2.14E-11  2
  2001DAN/AND3057-3063   (C2H5)2CHCHO + ·OH → Products  298   1.28           1.28  2
  Reference reaction:  1-C4H8 + ·OH → Products 2
  2001DAN/AND3057-3063   (C2H5)2CHCHO + ·OH → Products  298   4.02E-11           4.02E-11  2

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