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Author(s):   D'Anna, B.; Andresen, O.; Gefen, Z.; Nielsen, C.J.
Title:   Kinetic Study of OH and NO3 Radical Reactions with 14 Aliphatic Aldehydes
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   3057 - 3063
Year:   2001
Reference type:   Journal article
Squib:   2001DAN/AND3057-3063

Reaction:   neo-C5H11CHO + ·OH → Products
Reaction order:   2
Reference reaction:   1-C4H8 + ·OH → Products
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   2.14x10-11 [±1.4x10-12 cm3/molecule s]
Bath gas:   Air
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)
Comments:   OH generated photolysis of organic nitrites, followed by reaction of the organic radical with O2 to generate HO2, with subsequent reaction of NO with O2.k(OH + -butene) = 3.13E-11.

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