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Author(s):   Gao, Y.; Chen, Y.; Ma, X.; Chen, C.
Title:   The Collisional Quenching of CCl2(A 1B1 and a 3B1) by Substituted Methane Molecules
Journal:   Chem. Phys.
Volume:   269
Page(s):   389 - 397
Year:   2001
Reference type:   Journal article
Squib:   2001GAO/CHE389-397

Reaction:   CCl2 (A 1B1) + CH3Cl → CCl2 (a 3B1) + Products + CH3Cl + CCl2 (X 1A1)
Reaction order:   2
Temperature:   298 K
Pressure:  2.00E-3 bar
Rate expression:   4.31x10-10 [±2.2x10-11 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Temperatue not disclosed; 298 K assumed.

Rate coefficient includes contributions from electronic quenching to the X 1A1 and a 3B1 states and from chemical reaction. Uncertainty represents precision only.

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