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Author(s):   Herndon, S.C.; Gierczak, T.; Talukdar, R.K.; Ravishankara, A.R.
Title:   Kinetics of the Reactions of OH with Several Alkyl Halides
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   4529 - 4535
Year:   2001
Reference type:   Journal article
Squib:   2001HER/GIE4529-4535

Reaction:   CH3Cl + ·OH·CH2Cl + H2O
Reaction order:   2
Temperature:   224 - 398 K
Pressure:  2.67E-2 - 0.27 bar
Rate expression:   2.14x10-11 [±3.45x10-12 cm3/molecule s] (T/298 K)0.50 e-10061 [±432 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   somewhat different values of modified Arrhenius expression parameters are given in the abstract.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
224 8.37E-14
225 8.59E-14
250 1.55E-13
275 2.52E-13
300 3.80E-13
325 5.40E-13
350 7.31E-13
375 9.53E-13
398 1.18E-12