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Title: Kinetics of the Reactions of OH with Several Alkyl Halides
Journal: Phys. Chem. Chem. Phys.
Volume: 3
Page(s): 4529 - 4535
Year: 2001
Reference type: Journal article
Squib: 2001HER/GIE4529-4535
Reaction:
CH2Cl2 + ·OH → CHCl2 + H2O
Reaction order:
2
Temperature:
219 - 394
K
Pressure: 2.67E-2 - 0.27 bar
Rate expression:
1.14x10-11 [±1.04x10-12 cm3/molecule s] (T/298 K)0.50 e-5995 [±266 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 219 | 3.63E-13 |
| 225 | 4.02E-13 |
| 250 | 5.83E-13 |
| 275 | 7.95E-13 |
| 300 | 1.03E-12 |
| 325 | 1.29E-12 |
| 350 | 1.57E-12 |
| 375 | 1.87E-12 |
| 394 | 2.10E-12 |