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Author(s):   Marcy, T.P.; Diaz, R.R.; Heard, D.; Leone, S.R.; Harding, L.B.; Klippenstein, S.J.
Title:   Theoretical and Experimental Investigation of the Dynamics of the Production of CO from the CH3 + O and CD3 + O Reactions
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   8361 - 8369
Year:   2001
Reference type:   Journal article
Squib:   2001MAR/DIA8361-8369

Reaction:   ·CH3 + CO + H2 +
Reaction order:   2
Rate expression:   no rate data available
Category:  Other
Data type:   Other
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Chemiluminescence
Comments:   Measurements of the infrared emission from CO(v=1) product showed that deuteration of the methyl radical reduces the CO product fraction by 33%.

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