Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Marcy, T.P.; Diaz, R.R.; Heard, D.; Leone, S.R.; Harding, L.B.; Klippenstein, S.J.
Title:   Theoretical and Experimental Investigation of the Dynamics of the Production of CO from the CH3 + O and CD3 + O Reactions
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   8361 - 8369
Year:   2001
Reference type:   Journal article
Squib:   2001MAR/DIA8361-8369

Reaction:   ·CH3 + CO + H2 +
Reaction order:   2
Rate expression:   no rate data available
Category:  Other
Data type:   Other
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Chemiluminescence
Comments:   Measurements of the infrared emission from CO(v=1) product showed that deuteration of the methyl radical reduces the CO product fraction by 33%.

View full bibliographic record.