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Author(s):   Marcy, T.P.; Diaz, R.R.; Heard, D.; Leone, S.R.; Harding, L.B.; Klippenstein, S.J.
Title:   Theoretical and Experimental Investigation of the Dynamics of the Production of CO from the CH3 + O and CD3 + O Reactions
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   8361 - 8369
Year:   2001
Reference type:   Journal article
Squib:   2001MAR/DIA8361-8369

Reaction:   ·CH3 + CO + H2 +
Reaction order:   2
Rate expression:   no rate data available
Category:  Theory
Data type:   Other theoretical
Comments:   Trajectory calculations on a potential energy surface derived from ab initio results indicate that CO is a product from activated HCO, which is generated by H2 elimination from activated CH3O. Deuteration of the methyl radical reduces the CO product fraction.

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