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Accessibility information
Author(s):   Mereau, R.; Rayez, M.-T; Rayez, J.-C.; Caralp, F.; Lesclaux, R.
Title:   Theoretical Study on the Atmospheric Fate of Carbonyl Radicals: Kinetics of Decomposition Reactions
Journal:   Phys. Chem. Behav. Atmos. Pollut. Proc. Eur. Symp.
Volume:   3
Page(s):   4712 - 4717
Year:   2001
Reference type:   Journal article
Squib:   2001MER/RAY4712-4717

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2001MER/RAY4712-4717   CH3COCO + ·CH3  298   8.40E13       7.24E04   17.14  1
  2001MER/RAY4712-4717   CH3CH2COCO + ·C2H5  298   1.80E14       6.53E04   645  1
  2001MER/RAY4712-4717   (CH3)2CHC=O → CO + iso-C3H7  298   8.60E13       5.56E04   1.54E04  1
  2001MER/RAY4712-4717   (CH3)3CC(O)· → CO + tert-C4H9  298   5.90E13       4.77E04   2.57E05  1
  2001MER/RAY4712-4717   ClCH2C(O)(.) → CO + ·CH2Cl  298   9.20E13       5.69E04   9780  1
  2001MER/RAY4712-4717   CHCl2CO → CO + CHCl2  298   1.10E14       3.68E04   3.90E07  1
  2001MER/RAY4712-4717   CCl3C(O)(.) → CO + ·CCl3  298   1.30E14       2.55E04   4.41E09  1
  2001MER/RAY4712-4717   CF3C(O)CO + ·CF3  298   1.40E14       4.94E04   3.07E05  1
  2001MER/RAY4712-4717   HC(O)CO → CO + HCO  298   6.40E13       3.51E04   4.51E07  1
  2001MER/RAY4712-4717   CH3C(O)C(O)· → CO + CH3CO  298   1.40E14       2.80E04   1.73E09  1
  2001MER/RAY4712-4717   HOCH2C(·)O → CO + (·)CH2OH  298   5.30E13       4.89E04   1.42E05  1
  2001MER/RAY4712-4717   HO(CH3)2CCO → OCH(CH3)2 + CO  298   5.40E13       3.39E04   6.17E07  1
  2001MER/RAY4712-4717   CH2=CHC(·)OCO + C2H3  298   1.30E14       9.37E04   4.90E-03  1
  2001MER/RAY4712-4717   CH3OC(·)(O) → CO + CH3  298   5.00E13       9.62E04   6.87E-04  1
  2001MER/RAY4712-4717   CH3OC(·)(O) → CO2 + ·CH3  298   1.90E14       6.02E04   5332  1
  2001MER/RAY4712-4717   CH3COCO + ·CH3  298   3.50           3.50  1
  2001MER/RAY4712-4717   CH3CH2COCO + ·C2H5  298   320           320  1
  2001MER/RAY4712-4717   (CH3)2CHC=O → CO + iso-C3H7  298   1.10E04           1.10E04  1
  2001MER/RAY4712-4717   (CH3)3CC(O)· → CO + tert-C4H9  298   1.10E04           1.10E04  1
  2001MER/RAY4712-4717   ClCH2C(O)(.) → CO + ·CH2Cl  298   1500           1500  1
  2001MER/RAY4712-4717   CHCl2CO → CO + CHCl2  298   3.00E06           3.00E06  1
  2001MER/RAY4712-4717   CCl3C(O)(.) → CO + ·CCl3  298   1.40E08           1.40E08  1
  2001MER/RAY4712-4717   CF3C(O)CO + ·CF3  298   1.40E08           1.40E08  1
  2001MER/RAY4712-4717   HC(O)CO → CO + HCO  298   1.80E06           1.80E06  1
  2001MER/RAY4712-4717   CH3C(O)C(O)· → CO + CH3CO  298   7.40E07           7.40E07  1
  2001MER/RAY4712-4717   HOCH2C(·)O → CO + CH3  298   3.00E04           3.00E04  1
  2001MER/RAY4712-4717   HO(CH3)2CCO → CO + (CH3)2C(OH)  298   1.80E07           1.80E07  1
  2001MER/RAY4712-4717   CH2=CHC(·)OCO + C2H3  298   3.60E-03           3.60E-03  1
  2001MER/RAY4712-4717   CH3OC(·)(O) → CO + CH3  298   6.00E-04           6.00E-04  1
  2001MER/RAY4712-4717   CH3OC(·)(O) → CO2 + ·CH3  298   1000           1000  1

Search returned 30 records.