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Author(s):   Ninomiya, Y.; Goto, M.; Hashimoto, S.; Kawasaki, M.; Wallington, T.J.
Title:   Cavity Ring-Down Spectroscopic Study of the Kinetics of the Reactions of FCO Radicals with O2 and NO at 295 K
Journal:   Int J. Chem. Kinet.
Volume:   33
Page(s):   130 - 135
Year:   2001
Reference type:   Journal article
Squib:   2001NIN/GOT130-135

Reaction:   FCO + FCOCOF2 + CO
Reaction order:   2
Temperature:   295 K
Pressure:  6.00E-3 bar
Rate expression:   1.8x10-11 [±3.0x10-12 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Rate coefficient is derived using the absorption coefficient of FCO at 320.7 nm, ?igma?= 7.84 x10-19 cm2.

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