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Author(s):   Ramacher, B.; Orlando, J.J.; Tyndall, G.S.
Title:   Temperature-Dependent Rate Coefficient Measurements for the Reaction of Bromine Atoms with Trichloroethene, Ethene, Acetylene, and Tetrachloroethene in Air
Journal:   Int. J. Chem. Kinet.
Volume:   33
Page(s):   198 - 211
Year:   2001
Reference type:   Journal article
Squib:   2001RAM/ORL198-211

Reaction:   C2Cl4 + Br· → Bromo-tetrachloro-ethyl radical
Reaction order:   2
Reference reaction:   CH2O + Br·HCO + HBr
Reference reaction order:   2
Temperature:   228 - 298 K
Pressure:  0.93 bar
Rate expression:   1.2x10-16
Rate constant is an upper limit.
Bath gas:   Air
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In both real time and by end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Rate coefficients are determined relative to reactions Br+CH2O -> HCO + HBr, k=7.9E-12 exp(-580/T) or Br+ CH3CHO -> CH3CO+HBr, k=2.7E-11 exp(-567/T) cc/molecule s.

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