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Author(s):   Rowley, D.M.; Bloss, W.J.; Cox, T.; Jones, R.L.
Title:   Kinetics and Products of the IO + BrO Reaction
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   7855 - 7864
Year:   2001
Reference type:   Journal article
Squib:   2001ROW/BLO7855-7864

Reaction:   I + BrOBr· + IO
Reaction order:   2
Temperature:   295 K
Pressure:  1.01 bar
Rate expression:   1.3x10-11 [±1.2x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Rate coefficient exhibits no temperatre dependence between 235 K and 333 K but diminishes below 235 K.

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