Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2020 Accessibility information |
Title: Kinetics of the Gas-Phase Reactions of Alcohols, Aldehydes, Carboxylic Acids, and Water with the C13 Stabilized Criegee Intermediate Formed from Ozonolysis of 1-Tetradecene
Journal: J. Phys. Chem. A
Volume: 105
Page(s): 6129 - 6135
Year: 2001
Reference type: Journal article
Squib: 2001TOB/ZIE6129-6135
Reaction:
1-Tetradecene + O3 → Products
Reaction order:
2
Temperature:
296
K
Pressure: 0.99 bar
Rate expression:
2.2x10-17 [cm3/molecule s]
Bath gas:
Air
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Analytical technique:
Mass spectrometry
Comments:
Follow HPTA formed in the reaction of the stabilized Criegee intermediate with excess heptanoic acid. Estimated yield of 0.23. Monitored by thermal desorption particle beam mass spectrometry.
View full bibliographic record.