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Author(s):   Tobias, H.J.; Ziemann, P.J.
Title:   Kinetics of the Gas-Phase Reactions of Alcohols, Aldehydes, Carboxylic Acids, and Water with the C13 Stabilized Criegee Intermediate Formed from Ozonolysis of 1-Tetradecene
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   6129 - 6135
Year:   2001
Reference type:   Journal article
Squib:   2001TOB/ZIE6129-6135

Reaction:   1-Tetradecene + O3 → Products
Reaction order:   2
Temperature:   296 K
Pressure:  0.99 bar
Rate expression:   2.2x10-17 [cm3/molecule s]
Bath gas:   Air
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Analytical technique:   Mass spectrometry
Comments:   Follow HPTA formed in the reaction of the stabilized Criegee intermediate with excess heptanoic acid. Estimated yield of 0.23. Monitored by thermal desorption particle beam mass spectrometry.

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