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Author(s):   Tucceri, M.E.; Badenes, M.P.; Croce, A.E.; Cobos, C.J.
Title:   Experimental and Theoretical Study of the Recombination Reactions of FS(O2)O with FC(O)O and CO
Journal:   Phys. Chem. Chem. Phys.
Volume:   3
Page(s):   1832 - 1839
Year:   2001
Reference type:   Journal article
Squib:   2001TUC/BAD1832-1839

Reaction:   M + FSO3 + FC(O)O· → M + FC(O)OO(O2)SF
Reaction order:   3
Temperature:   296 K
Rate expression:   1.0x10-12 [±1.0x10-13 cm6/molecule2 s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

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