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Author(s):   Arunan, E.; Vijayalakshmi, S.P.; Valera, R.; Setser, D.W.
Title:   Infrared Chemiluminescence: Evidence for Adduct Formation in the H + CH2XI Reaction and Studies of the N + CH2X (X=Cl/F/I/H) Reactions
Journal:   Phys. Chem. Chem. Phys.
Volume:   4
Page(s):   51 - 59
Year:   2002
Reference type:   Journal article
Squib:   2002ARU/VIJ51-59

Reaction:   + CH2Cl-I → ·CH2Cl + HCl
Reaction order:   2
Temperature:   300 K
Pressure:  8.00E-4 - 2.67E-3 bar
Rate expression:   5.0x10-12 [±2.0x10-12 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Mechanistic information only
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Other (IR)
Comments:   1) Relative HCl emission intensity suggets that reaction rate of this channel is four times smaller than for H + Cl2 --> Cl + HCl.2) Extensive thermochemical analysis is provided. Reaction is estimated to have a reaction enthalpy of reaction ?ELTA?r = -104.6 kJ mole-1.

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