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Author(s):   Belmekki, N. Glaude, P.A.; Da Costa, I.; Fournet, R.; Battin-Leclerc, F.
Title:   Experimental and Modeling Study of the Oxidation of 1-Butyne and 2-Butyne
Journal:   Int J. Chem. Kinet.
Volume:   34
Page(s):   172 - 183
Year:   2002
Reference type:   Journal article
Squib:   2002BEL/DAC172-183

Reaction:   CHCCH2CH2· → Vinylacetylene +
Reaction order:   1
Temperature:   1100 - 1600 K
Pressure:  6.38 - 9.22 bar
Rate expression:   4.0x1013 [s-1] e-162339 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 7.82E5
1150 1.69E6
1200 3.43E6
1250 6.58E6
1300 1.20E7
1350 2.09E7
1400 3.51E7
1450 5.68E7
1500 8.89E7
1550 1.35E8
1600 2.01E8