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Title: Experimental and Modeling Study of the Oxidation of 1-Butyne and 2-Butyne
Journal: Int J. Chem. Kinet.
Volume: 34
Page(s): 172 - 183
Year: 2002
Reference type: Journal article
Squib: 2002BEL/DAC172-183
Reaction:
CHCCH2CH2· → Vinylacetylene + H·
Reaction order:
1
Temperature:
1100 - 1600
K
Pressure: 6.38 - 9.22 bar
Rate expression:
4.0x1013 [s-1] e-162339 [J/mole]/RT
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1100 | 7.82E5 |
| 1150 | 1.69E6 |
| 1200 | 3.43E6 |
| 1250 | 6.58E6 |
| 1300 | 1.20E7 |
| 1350 | 2.09E7 |
| 1400 | 3.51E7 |
| 1450 | 5.68E7 |
| 1500 | 8.89E7 |
| 1550 | 1.35E8 |
| 1600 | 2.01E8 |