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Author(s):   Bloss, W.J.; Rowley, D.M.; Cox, R.A.; Jones, R.L.
Title:   Rate Coefficient for the BrO + HO2 Reaction at 298 K
Journal:   Phys. Chem. Chem. Phys.
Volume:   4
Page(s):   3639 - 3647
Year:   2002
Reference type:   Journal article
Squib:   2002BLO/ROW3639-3647

Reaction:   [CH3OH..HO2] complex + HO2CH3OH + H2O2 + O2
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   3.2x10-11 [±5.0x10-12 cm3/molecule s]
Bath gas:   O2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   O2 pressure is 1 atm. Uncertainty appears to include precision contributions only. Rate coefficient is derived using a model postulating that the reaction, HO2 + CH3OH <--> [CH3OH..HO2] complex, is at equilibrium.

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