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Author(s):   Bonard, A.; Daele, V.; Delfau, J.-L; Vovelle, C.
Title:   Kinetics of OH Radical Reactions with Methane in the Temperature Range 295-660 K and with Dimethyl Ether and Methyl-tert-butyl Ether in the Temperature Range 295-618 K
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   4384 - 4389
Year:   2002
Reference type:   Journal article
Squib:   2002BON/DAE4384-4389

Reaction:   tert-C4H9OCH3 + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   230 - 750 K
Rate expression:   2.81x10-13 [±1.6x10-14 cm3/molecule s] (T/298 K)2.93 e5953 [±150 J/mole]/RT
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
230 2.95E-12
250 2.94E-12
300 3.11E-12
350 3.48E-12
400 3.98E-12
450 4.61E-12
500 5.35E-12
550 6.21E-12
600 7.19E-12
650 8.30E-12
700 9.53E-12
750 1.09E-11