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Author(s):   Bryukov, M.G.; Slagle, I.R.; Knyazev, V.D.
Title:   Kinetics of Reactions of Cl Atoms with Methane and Chlorinated Methanes
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   10532 - 10542
Year:   2002
Reference type:   Journal article
Squib:   2002BRY/SLA10532-10542

Reaction:   CH2Cl2 + ClCHCl2 + HCl
Reaction order:   2
Temperature:   296 - 790 K
Pressure:  2.53E-3 - 9.73E-3 bar
Rate expression:   1.2x10-12 [cm3/molecule s] (T/298 K)1.58 e-2993 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 3.52E-13
300 3.66E-13
325 4.55E-13
350 5.54E-13
375 6.61E-13
400 7.77E-13
425 9.02E-13
450 1.03E-12
475 1.18E-12
500 1.32E-12
525 1.48E-12
550 1.64E-12
575 1.81E-12
600 1.99E-12
625 2.18E-12
650 2.37E-12
675 2.56E-12
700 2.77E-12
725 2.98E-12
750 3.19E-12
775 3.42E-12
790 3.55E-12