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Accessibility information
Author(s):   Carl, S.A.; Sun, Q.; Vereecken, L.; Peeters, J.
Title:   Absolute rate coefficient of the HCCO plus NO reaction over the range T=297-802 K
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   12242 - 12247
Year:   2002
Reference type:   Journal article
Squib:   2002CAR/SUN12242-12247

Reaction:   NO + HCCOCO + HC-N=O
Reaction order:   2
Temperature:   296 - 2000 K
Pressure:  7.20E-3 bar
Rate expression:   1.4x10-11 [±2.0x10-12 cm3/molecule s] e2661 [±249 J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation
Pressure dependence:   None reported

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 4.13E-11
300 4.07E-11
400 3.12E-11
500 2.66E-11
600 2.39E-11
700 2.21E-11
800 2.09E-11
900 2.00E-11
1000 1.93E-11
1100 1.87E-11
1200 1.83E-11
1300 1.79E-11
1400 1.76E-11
1500 1.73E-11
1600 1.71E-11
1700 1.69E-11
1800 1.67E-11
1900 1.66E-11
2000 1.64E-11