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Chemical Sciences Division
Greenslade, M.E.; Tsiouris, M.; Bonn, R.T.; Lester, M.I.|
Electronic Spectroscopy of the OH-CO Reactant Complex
Chem. Phys. Lett.
203 - 209
CO + ·OH → [OH...CO] complex
no rate data available
Laser induced fluorescence
A broad and relatively unstructured electronic excitation spectrum was observed for the [OH..CO] reactant complex in the OH A? (1,0) region by laser-induced fluorescence and fluorescence depletion methods. The electronic spectrum spans from 33,500 to 36,050 cm-1 and peaks near 34,600 cm-1. The electronic spectrum is consistent with a Franck?ondon mapping of the ground state radial distribution on a strongly attractive excited state potential that undergoes rapid decay dynamics.
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