Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Heimann, G.; Benkelberg, H.-J.; Boge, O.; Warneck, P.
Title:   Photodecomposition of Iodopentanes in Air: Product Distributions from the Self-Reactions of n-Pentyl Peroxyl Radicals
Journal:   Int J. Chem. Kinet.
Volume:   34
Page(s):   126 - 138
Year:   2002
Reference type:   Journal article
Squib:   2002HEI/BEN126-138

Reaction:   n-C5H11O· → CH2O + n-C4H9
Reaction order:   1
Reference reaction:   O2 + n-C5H11O· → n-C4H9CHO + HO2
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   5.1x1018 [±5.0x1017 molecule/cm3]
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.