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Accessibility information
Author(s):   Hippler, H.; Viskolcz, B.
Title:   Competition Between Alkyl Radical Addition to Carbonyl Bonds and H-Atom Abstraction Reactions
Journal:   Phys. Chem. Chem. Phys.
Volume:   4
Page(s):   4663 - 4668
Year:   2002
Reference type:   Journal article
Squib:   2002HIP/VIS4663-4668

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2002HIP/VIS4663-4668   CH2O + CH3  298           2.20E04   0.00E00  2
  2002HIP/VIS4663-4668   CH2O + ·CH3CH3CH2  298           3.30E04   0.00E00  2
  2002HIP/VIS4663-4668   CH2O + ·C2H5n-C3H7O  298           2.09E04   0.00E00  2
  2002HIP/VIS4663-4668   CH2O + n-C3H7n-C4H9O  298           2.36E04   0.00E00  2
  2002HIP/VIS4663-4668   CH2O + n-C4H9 → n-C5H11  298           1.60E04   0.00E00  2
  2002HIP/VIS4663-4668   CH2O + iso-C3H7 → (CH3)2CHCH2O  298           5300   0.00E00  2
  2002HIP/VIS4663-4668   CH2O + tert-C4H9 → (CH3)3CCH2  298           -9000   0.00E00  2
  2002HIP/VIS4663-4668   CH3CHO + CH3CH2  298           2.24E04   0.00E00  2
  2002HIP/VIS4663-4668   CH3CHO + ·CH3i-C3H7O  298           3.93E04   0.00E00  2
  2002HIP/VIS4663-4668   CH3CHO + CH3CH2 → 2-C4H9O  298           2.75E04   0.00E00  2
  2002HIP/VIS4663-4668   CH3CHO + n-C3H7 → CH3(CH2)2CH(CH3)O  298           2.79E04   0.00E00  2
  2002HIP/VIS4663-4668   CH3CHO + iso-C3H7 → (CH3)2CHCH(CH3)O  298           1.49E04   0.00E00  2
  2002HIP/VIS4663-4668   (CH3)2CO + i-C3H7O  298           4.16E04   0.00E00  2
  2002HIP/VIS4663-4668   (CH3)2CO + ·CH3 → (CH3)3CO  298           4.45E04   0.00E00  2
  2002HIP/VIS4663-4668   (CH3)2CO + CH3CH2 → CH3CH2C(CH3)2O(·)  298           3.50E04   0.00E00  2
  2002HIP/VIS4663-4668   C2H5CHO + ·CH3 → 2-C4H9O  298           4.38E04   0.00E00  2
  2002HIP/VIS4663-4668   n-C3H7CHO + ·CH3 → CH3(CH2)2CH(CH3)O  298           4.19E04   0.00E00  2

Search returned 17 records.