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Accessibility information
Author(s):   Olleta, A.C.; Lane, S.I.
Title:   A Theoretical Study of Hydrogen and Chlorine Transfer Reactions from Fluorine- and Chlorine-Substituted Methanes by F3C. Radicals
Journal:   Phys. Chem. Chem. Phys.
Volume:   4
Page(s):   3341 - 3349
Year:   2002
Reference type:   Journal article
Squib:   2002OLL/LAN3341-3349

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2002OLL/LAN3341-3349   CHF3 + ·CF3CHF3 + ·CF3  448 - 636   1.05E-12       6.06E04      2
  2002OLL/LAN3341-3349   CH2F2 + ·CF3CHF3 + ·CHF2  448 - 636   7.08E-13       4.72E04      2
  2002OLL/LAN3341-3349   CH3F + ·CF3CHF3 + ·CH2F  469 - 633   9.55E-13       4.69E04      2
  2002OLL/LAN3341-3349   CHCl3 + ·CF3CHF3 + ·CCl3  367 - 569   1.23E-13       2.78E04      2
  2002OLL/LAN3341-3349   CHCl3 + ·CF3CF3Cl + CHCl2  367 - 569   3.02E-13       4.47E04      2
  2002OLL/LAN3341-3349   CH2Cl2 + ·CF3CHF3 + CHCl2  358 - 507   1.41E-13       2.74E04      2
  2002OLL/LAN3341-3349   CH2Cl2 + ·CF3CF3Cl + ·CH2Cl  358 - 477   1.32E-13       5.37E04      2
  2002OLL/LAN3341-3349   CH3Cl + ·CF3CHF3 + ·CH2Cl  416 - 578   4.37E-13       4.17E04      2
  2002OLL/LAN3341-3349   CH3Cl + ·CF3CF3Cl + ·CH3  416 - 578   3.16E-13       6.06E04      2
  2002OLL/LAN3341-3349   CF2Cl2 + ·CF3CF3Cl + ·CClF2  533 - 613   3.89E-13       5.62E04      2
  2002OLL/LAN3341-3349   CFCl3 + ·CF3CF3Cl + ·CCl2F  503 - 613   1.41E-12       4.56E04      2
  2002OLL/LAN3341-3349   CCl4 + ·CF3CF3Cl + ·CCl3  369 - 513   2.40E-12       3.33E04      2

Search returned 12 records.