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Accessibility information
Author(s):   Olleta, A.C.; Lane, S.I.
Title:   A Theoretical Study of Hydrogen and Chlorine Transfer Reactions from Fluorine- and Chlorine-Substituted Methanes by F3C. Radicals
Journal:   Phys. Chem. Chem. Phys.
Volume:   4
Page(s):   3341 - 3349
Year:   2002
Reference type:   Journal article
Squib:   2002OLL/LAN3341-3349

Reaction:   CH2F2 + ·CF3CHF3 + ·CHF2
Reaction order:   2
Temperature:   448 - 636 K
Rate expression:   7.08x10-13 [cm3/molecule s] e-47237 [J/mole]/RT
Category:  Theory
Data type:   Ab initio
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
448 2.20E-18
450 2.33E-18
475 4.53E-18
500 8.23E-18
525 1.41E-17
550 2.31E-17
575 3.62E-17
600 5.47E-17
625 7.99E-17
636 9.35E-17