Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Picquet-Varrault, B.; Dossin, J.F.; Durand-Jolibois, R.; Carlier, P.
Title:   FTIR Spectroscopic Study of the OH-Induced Oxidation of Isopropyl, Isobutyl, and tert-Butyl Acetates
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   2895 - 2902
Year:   2002
Reference type:   Journal article
Squib:   2002PIC/DOS2895-2902

Reaction:   isobutyl acetate + ·OH → Products
Reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Atmospheric pressure pyrex reactor, continuous photolysis of methyl nitrite for OH, FTIR monitoring of products, mechanistic information and product yields only, from isobutyl acetate - acetone 0.78 (0.12), formic acetic anhydride 0.52 (0.06), acetoxyacetaldehyde 0.18 (0.06), acetic acid 0.08 (0.02), and peroxyisobutyryl nitrate, also gives integrated band intensities of a number of compounds

View full bibliographic record.