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Author(s):   Sheng, C.Y.; Bozzelli, J.W.; Dean, A.M.; Chang, A.Y.
Title:   Detailed Kinetics and Thermochemistry of C2H5 + O2: Reaction Kinetics of the Chemically-Activated and Stabilized CH3CH2OO. Adduct
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   7276 - 7293
Year:   2002
Reference type:   Journal article
Squib:   2002SHE/BOZ7276-7293

Reaction:   C2H5OO·CH3CHO + ·OH
Reaction order:   1
Temperature:   250 - 2500 K
Rate expression:   3.24x1012 [s-1] (T/298 K)1.37 e-174013 [J/mole]/RT
Category:  Theory
Data type:   Ab initio
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
250 1.12E-24
300 1.65E-18
400 9.17E-11
500 4.36E-6
600 6.00E-3
700 1.08E0
800 5.45E1
900 1.17E3
1000 1.38E4
1100 1.06E5
1200 5.82E5
1300 2.48E6
1400 8.68E6
1500 2.58E7
1600 6.75E7
1700 1.58E8
1800 3.39E8
1900 6.74E8
2000 1.25E9
2100 2.21E9
2200 3.70E9
2300 5.95E9
2400 9.21E9
2500 1.38E10