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Author(s):   Sorensen, M.; Hurley, M.D.; Wallington, T.J.; Dibble, T.S.; Nielsen, O.J.
Title:   Do Aerosols Act As Catalysts in the OH Radical Initiated Atmospheric Oxidation of Volatile Organic Compounds?
Journal:   Atmos. Environ.
Volume:   36
Page(s):   5947 - 5952
Year:   2002
Reference type:   Journal article
Squib:   2002SOR/HUR5947-5952

Reaction:   CH3OH + ·OH → Products
Reaction order:   2
Reference reaction order:   2
Temperature:   296 K
Pressure:  1.00 bar
Rate expression:   8.12x10-13±5.4x10-14
Bath gas:   air
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Sensitized photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Acetylene and ethene were the reference compounds.Effect of NaCl and NH4NO3 aerosols on the reaction rate was investigated.No effect has been found.

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