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Author(s):   Su, M.-C.; Kumaran, S.S.; Lim, K.P.; Michael, J.V.; Wagner, A.F.; Harding, L.B.; Fang, D.-C.
Title:   Rate Constants, 1100<=T<=2000K, for H + NO2 -> OH + NO Using Two Shock Tube Techniques: Comparison of Theory to Experiment
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   8261 - 8270
Year:   2002
Reference type:   Journal article
Squib:   2002SU/KUM8261-8270

Reaction:   NO2 + ·OH + NO
Reaction order:   2
Temperature:   1100 - 1650 K
Pressure:  0.16 - 0.68 bar
Rate expression:   1.4x10-10 [±3.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Other (Vis-UV)
Comments:   Shock tube, thermal C2H5I -> H decomposition to initiate, probed by H atomic resonance absorbance in pseudo-first order with high NO2, 1 sigma errors

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