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Author(s):   Yamasaki, K.; Watanabe, A.; Tanaka, A.; Sato, M.; Tokue, I.
Title:   Kinetics of the Reaction NH2(X~2B1, v2 = 0 and 1) + NO
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   6563 - 6569
Year:   2002
Reference type:   Journal article
Squib:   2002YAM/WAT6563-6569

Reaction:   NH2(X2B1 v2 = 1) + CF4 → NH2(X2B1 v2 = 0) + CF4
Reaction order:   2
Temperature:   298 K
Pressure:  1.33E-3 bar
Rate expression:   3.2x10-11 [±5.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   193 nm laser photolysis of NH3 / LIF of v = 0 and v = 1 states, errors are 2 sigma statistical, a bit larger than analgous ND2 rate coefficient previously reported by Chichinin, et al.

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