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Author(s):   Zhang, Q.; Zhang, D.; Wang, S.; Gu, Y.
Title:   Ab Initio and Kinetic Calculations for the Reactions of H with (CH3)(4-n)GeHn (n=1,2,3,4)
Journal:   J. Phys. Chem. A
Volume:   106
Page(s):   122 - 129
Year:   2002
Reference type:   Journal article
Squib:   2002ZHA/ZHA122-129

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2002ZHA/ZHA122-129   GeH4 + H2 + GeH3  300 - 2000   4.79E-12   2.16   2444      2
  2002ZHA/ZHA122-129   CH3GeH3 + H2 + *GeH2CH3  300 - 2000   6.87E-12   2.22   1347      2
    2002ZHA/ZHA122-129   CH3GeH3 + H2 + GeH3CH2*                     2
  2002ZHA/ZHA122-129   (CH3)2GeH2: + H2 + *GeH(CH3)2  300 - 2000   4.85E-12   2.18   898      2
    2002ZHA/ZHA122-129   (CH3)2GeH2: + → GeH2(CH3)CH2* + H2                     2
  2002ZHA/ZHA122-129   (CH3)3GeH + H2 + (CH3)3Ge  300 - 2000   3.88E-12   2.33   499      2
    2002ZHA/ZHA122-129   (CH3)3GeH + H2 + GeH(CH3)2CH2*                     2

Search returned 7 records.