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Author(s):   Andersen, M.PS.; Hurley, M.D.; Wallington, T.J.; Ball, J.C.; Martin, J.W.; Ellis, D.A.; Mabury, S.A.
Title:   Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O2+HO2 reaction
Journal:   Chem. Phys. Lett.
Volume:   381
Page(s):   14 - 21
Year:   2003
Reference type:   Journal article
Squib:   2003AND/HUR14-21

Reaction:   C2F5C(O)O2 + HO2 → C2F5C(O)O + ·OH + O2
Reaction order:   2
Reference reaction:   C2F5C(O)O2 + HO2 → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   7.6x10-1±4.0x10-2
Rate constant is an upper limit.
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Sensitized photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)

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