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Accessibility information
Author(s):   Atkinson, R.
Title:   Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes
Journal:   Atmos. Chem. Phys.
Volume:   3
Page(s):   2233 - 2307
Year:   2003
Reference type:   Journal article
Squib:   2003ATK2233-2307

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003ATK2233-2307   CH4 + ·OH → Other Products + H2O  190 - 1240   1.76E-13   2.82   8206   6.40E-15  2
  2003ATK2233-2307   CH3D + ·OH → Other Products + H2O  240 - 430   4.61E-13   2.00   1.11E04   5.28E-15  2
  2003ATK2233-2307   CH2D2 + ·OH → Other Products + H2O  270 - 360   2.18E-12       1.60E04   3.40E-15  2
  2003ATK2233-2307   CHD3 + ·OH → Other Products + H2O  270 - 360   1.46E-12       1.64E04   1.95E-15  2
  2003ATK2233-2307   CD4 + ·OH → Other Products + H2O  240 - 800   5.06E-13   2.00   1.56E04   9.15E-16  2
  2003ATK2233-2307   C2H6 + ·OH → Other Products + H2O  180 - 1230   1.32E-12   2.00   4149   2.48E-13  2
  2003ATK2233-2307   C3H8 + ·OH → Other Products + H2O  190 - 1220   1.47E-12   2.00   723   1.09E-12  2
  2003ATK2233-2307   1-C4H10 + ·OH → Other Products + H2O  230 - 760   1.61E-12   2.00   -948   2.36E-12  2
  2003ATK2233-2307   iso-C4H10 + ·OH → Other Products + H2O  210 - 1150   1.04E-12   2.00   -1771   2.12E-12  2
  2003ATK2233-2307   n-C5H12 + ·OH → Other Products + H2O  220 - 760   2.24E-12   2.00   -1314   3.80E-12  2
  2003ATK2233-2307   neo-C5H12 + ·OHNeopentyl + H2O  280 - 910   1.65E-12   2.00   1721   8.25E-13  2
  2003ATK2233-2307   1-C6H14 + ·OH → Other Products + H2O  290 - 970   7.57E-12   1.00   931   5.20E-12  2
  2003ATK2233-2307   (CH3)3CCH2CH3 + ·OH → Other Products + H2O  240 - 330   3.37E-11       6726   2.23E-12  2
  2003ATK2233-2307   (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O  240 - 1220   1.47E-12   2.00   -3384   5.78E-12  2
  2003ATK2233-2307   1-C7H16 + ·OH → Other Products + H2O  290 - 1090   1.73E-12   2.00   -3376   6.76E-12  2
  2003ATK2233-2307   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  240 - 760   8.17E-13   2.00   -3816   3.81E-12  2
  2003ATK2233-2307   n-C8H18 + ·OH → Other Products + H2O  290 - 1080   2.42E-12   2.00   -3002   8.11E-12  2
  2003ATK2233-2307   (CH3)2CHCH2C(CH3)3 + ·OH → Other Products + H2O  290 - 1190   2.09E-12   2.00   -1164   3.34E-12  2
  2003ATK2233-2307   (CH3)3CC(CH3)3 + ·OHH2O + (CH3)3CC(CH3)2CH2  290 - 1180   1.77E-12   2.00   1480   9.72E-13  2
  2003ATK2233-2307   n-C9H20 + ·OH → Other Products + H2O  290 - 1100   2.25E-12   2.00   -3625   9.70E-12  2
  2003ATK2233-2307   1-C10H22 + ·OH → Other Products + H2O  290 - 1110   2.82E-12   2.00   -3376   1.10E-11  2
  2003ATK2233-2307   Cyclopropane + ·OHCyclopropyl + H2O  200 - 460   3.74E-13   2.00   3775   8.15E-14  2
  2003ATK2233-2307   Cyclobutane + ·OHCyclobutyl + H2O  270 - 370   1.86E-12   2.00   -208   2.03E-12  2
  2003ATK2233-2307   Cyclopentane + ·OHCyclopentyl + H2O  270 - 1200   2.42E-12   2.00   -1779   4.97E-12  2
  2003ATK2233-2307   Cyclohexane + ·OHCyclohexyl + H2O  290 - 500   2.90E-12   2.00   -2178   6.97E-12  2
  2003ATK2233-2307   CH4 + ·OH → Other Products + H2O  298   6.40E-15           6.40E-15  2
  2003ATK2233-2307   CH3D + ·OH → Other Products + H2O  298   5.28E-15           5.28E-15  2
  2003ATK2233-2307   CH2D2 + ·OH → Other Products + H2O  298   3.40E-15           3.40E-15  2
  2003ATK2233-2307   CHD3 + ·OH → Other Products + H2O  298   1.95E-15           1.95E-15  2
  2003ATK2233-2307   CD4 + ·OH → Other Products + H2O  298   9.16E-16           9.16E-16  2
  2003ATK2233-2307   C2H6 + ·OH → Other Products + H2O  298   2.48E-13           2.48E-13  2
  2003ATK2233-2307   C3H8 + ·OH → Other Products + H2O  298   1.09E-12           1.09E-12  2
  2003ATK2233-2307   1-C4H10 + ·OH → Other Products + H2O  298   2.36E-12           2.36E-12  2
  2003ATK2233-2307   iso-C4H10 + ·OH → Other Products + H2O  298   2.12E-12           2.12E-12  2
  2003ATK2233-2307   n-C5H12 + ·OH → Other Products + H2O  298   3.80E-12           3.80E-12  2
  2003ATK2233-2307   iso-C5H12 + ·OH → Other Products + H2O  298   3.60E-12           3.60E-12  2
  2003ATK2233-2307   neo-C5H12 + ·OHNeopentyl + H2O  298   8.25E-13           8.25E-13  2
  2003ATK2233-2307   1-C6H14 + ·OH → Other Products + H2O  298   5.20E-12           5.20E-12  2
  2003ATK2233-2307   (CH3)2CH(CH2)2CH3 + ·OH → Other Products + H2O  298   5.20E-12           5.20E-12  2
  2003ATK2233-2307   (C2H5)2CHCH3 + ·OH → Other Products + H2O  298   5.20E-12           5.20E-12  2
  2003ATK2233-2307   (CH3)3CCH2CH3 + ·OH → Other Products + H2O  298   2.23E-12           2.23E-12  2
  2003ATK2233-2307   (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O  298   5.78E-12           5.78E-12  2
  2003ATK2233-2307   1-C7H16 + ·OH → Other Products + H2O  298   6.76E-12           6.76E-12  2
  2003ATK2233-2307   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  298   3.81E-12           3.81E-12  2
  2003ATK2233-2307   n-C8H18 + ·OH → Other Products + H2O  298   8.11E-12           8.11E-12  2
  2003ATK2233-2307   (CH3)2CHCH2C(CH3)3 + ·OH → Other Products + H2O  298   3.34E-12           3.34E-12  2
  2003ATK2233-2307   (CH3)3CC(CH3)3 + ·OHH2O + (CH3)3CC(CH3)2CH2  298   9.72E-13           9.72E-13  2
  2003ATK2233-2307   n-C9H20 + ·OH → Other Products + H2O  298   9.70E-12           9.70E-12  2
  2003ATK2233-2307   Pentane, 3,3-diethyl- + ·OH → Other Products + H2O  298   4.80E-12           4.80E-12  2
  2003ATK2233-2307   1-C10H22 + ·OH → Other Products + H2O  298   1.10E-11           1.10E-11  2
  2003ATK2233-2307   n-C11H24 + ·OH → Other Products + H2O  298   1.23E-11           1.23E-11  2
  2003ATK2233-2307   CH3(CH2)10CH3 + ·OH → Other Products + H2O  298   1.32E-11           1.32E-11  2
  2003ATK2233-2307   CH3(CH2)11CH3 + ·OH → Other Products + H2O  298   1.51E-11           1.51E-11  2
  2003ATK2233-2307   Cyclopropane + ·OHCyclopropyl + H2O  298   8.15E-14           8.15E-14  2
  2003ATK2233-2307   Cyclobutane + ·OHCyclobutyl + H2O  298   2.03E-12           2.03E-12  2
  2003ATK2233-2307   Cyclopentane + ·OHCyclopentyl + H2O  298   4.97E-12           4.97E-12  2
  2003ATK2233-2307   Cyclohexane + ·OHCyclohexyl + H2O  298   6.97E-12           6.97E-12  2

Search returned 57 records.