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Accessibility information
Author(s):   Cardelino, B.H.; Moore, C.E.; Cardelino, C.A.; McCall, S.D.; Frazier, D.O.; Bachmann, K.J.
Title:   Semiclassical Calculation of Reaction Rate Constants for Homolytical Dissociation Reactions of Interest in Organometallic Vapor-Phase Epitaxy (OMPE)
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   3708 - 3718
Year:   2003
Comments:   NOTE: The units of the bimolecular reaction rates are never stated. The best fit with experimental data for trhe CH3+CH3 -> C2H6 indicates that this rates are in liter mole/second.
Reference type:   Journal article
Squib:   2003CAR/MOO3708-3718

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003CAR/MOO3708-3718   In(CH3)3·CH3 + In(CH3)2  700 - 1000   1.08E16       1.97E05      1
  2003CAR/MOO3708-3718   In(CH3)3·CH3 + In(CH3)2  700 - 1000   1.28E18       2.12E05      1
  2003CAR/MOO3708-3718   ·CH3 + In(CH3)2 → In(CH3)3  700 - 1000   6.58E-15       -4.77E04      2
  2003CAR/MOO3708-3718   ·CH3 + In(CH3)2 → In(CH3)3  700 - 1000   1.53E-11       -3.28E04      2
  2003CAR/MOO3708-3718   In(CH3)2 → InCH3(singlet) + ·CH3  700 - 1000   3.38E08       5.50E04      1
  2003CAR/MOO3708-3718   In(CH3)2 → InCH3(singlet) + ·CH3  700 - 1000   6.73E09       5.50E04      1
  2003CAR/MOO3708-3718   InCH3(singlet) + ·CH3 → In(CH3)2  700 - 1000   3.50E-19       -4.57E04      2
  2003CAR/MOO3708-3718   InCH3(singlet) + ·CH3 → In(CH3)2  700 - 1000   1.40E-16       -4.57E04      2
  2003CAR/MOO3708-3718   In(CH3)2 → InCH3(triplet) + ·CH3  700 - 1000   1.03E14       2.45E05      1
  2003CAR/MOO3708-3718   In(CH3)2 → InCH3(triplet) + ·CH3  700 - 1000   2.06E15       2.45E05      1
  2003CAR/MOO3708-3718   InCH3(triplet) + ·CH3 → In(CH3)2  700 - 1000   3.32E-14       -4.64E04      2
  2003CAR/MOO3708-3718   InCH3(triplet) + ·CH3 → In(CH3)2  700 - 1000   1.33E-11       -4.64E04      2
  2003CAR/MOO3708-3718   InCH3(singlet) → ·CH3 + In  700 - 1000   9.45E13       2.20E05      1
  2003CAR/MOO3708-3718   InCH3(singlet) → ·CH3 + In  700 - 1000   1.86E15       2.20E05      1
  2003CAR/MOO3708-3718   ·CH3 + In → InCH3(singlet)  700 - 1000   3.12E-13       8.10E04      2
  2003CAR/MOO3708-3718   ·CH3 + In → InCH3(singlet)  700 - 1000   1.24E-10       8.10E04      2
  2003CAR/MOO3708-3718   InCH3(triplet) → ·CH3 + In  700 - 1000   2.95E07       1.01E04      1
  2003CAR/MOO3708-3718   InCH3(triplet) → ·CH3 + In  700 - 1000   5.93E08       1.01E04      1
  2003CAR/MOO3708-3718   ·CH3 + In → InCH3(triplet)  700 - 1000   3.17E-19       6.15E04      2
  2003CAR/MOO3708-3718   ·CH3 + In → InCH3(triplet)  700 - 1000   1.25E-16       6.15E04      2
  2003CAR/MOO3708-3718   C2H6·CH3 + ·CH3  700 - 1000   3.47E14       3.19E05      1
  2003CAR/MOO3708-3718   C2H6·CH3 + ·CH3  700 - 1000   6.97E15       3.19E05      1
  2003CAR/MOO3708-3718   ·CH3 + ·CH3C2H6  700 - 1000   1.57E-17       -4.02E04      2
  2003CAR/MOO3708-3718   ·CH3 + ·CH3C2H6  700 - 1000   6.19E-15       -4.02E04      2
  2003CAR/MOO3708-3718   In(CH3)3·CH3 + In(CH3)2  550 - 663   4.00E20       2.29E05      1
  2003CAR/MOO3708-3718   InCH3(singlet) → ·CH3 + In  680 - 781   1.30E17       2.12E05      1
  2003CAR/MOO3708-3718   (CH3)3Ga·CH3 + (CH3)2Ga  686 - 839   2.10E20       2.69E05      1
  2003CAR/MOO3708-3718   (CH3)3Ga·CH3 + (CH3)2Ga  300 - 600   2.10E21       2.80E05      1
  2003CAR/MOO3708-3718   (CH3)2Ga → ·CH3 + CH3Ga  829 - 983   1.60E20       3.07E05      1
  2003CAR/MOO3708-3718   Al(CH3)3 → Al(CH3)2 + ·CH3  850 - 950   5.40E19       2.95E05      1
  2003CAR/MOO3708-3718   AsH3 + AsH2·  850 - 950   1.40E18       3.01E05      1
  2003CAR/MOO3708-3718   PH3 + PH2  850 - 950   1.90E18       3.33E05      1
  2003CAR/MOO3708-3718   NH3 + NH2  2200 - 3300   6.60E17       4.07E05      1

Search returned 33 records.