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Author(s):   Dagaut, P.; Lecomte, F.; Mieritz, J.; Glarborg, P.
Title:   Experimental and Kinetic Modeling Study of the Effect of NO and SO2 on the Oxidation of CO-H2 Mixtures
Journal:   J. Phys. Chem. A
Volume:   35
Page(s):   564 - 575
Year:   2003
Reference type:   Journal article
Squib:   2003DAG/LEC564-575

Reaction:   SO2 + → HSO2
Reaction order:   3
Rate expression:   no rate data available
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Comments:   No measured rate constants. Work is measurements and modeling of CO/H2 reaction mixture measured in a jet-stirred reactor and in a laminar flow reactor. Measured concentration profiles as a function of temperature using GC and FTIR> The effect of NO and SO2 were studied. Atmospheric pressures were used, lean to rich mixtures were studied and temperatures of 800-1400 K. A detailed chemical kinetic model was developed/refined. Used theoretical rate constant from Goumri et al JPC A 103, 11328 (1999) for SO2 + H -> HOSO.

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