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Author(s):   Decker, B.K.; Macdonald, R.G.
Title:   Determination of the Rate Constant for the Radical-Radical Reaction CN(x2Σ +) + OH(x2PI) at 292 K
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   9137 - 9146
Year:   2003
Reference type:   Journal article
Squib:   2003DEC/MAC9137-9146

Reaction:   CN + ·OH → Products
Reaction order:   2
Temperature:   292 K
Pressure:  4.00E-3 - 8.00E-3 bar
Rate expression:   1.4x10-10 [±4.8x10-11 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Other (direct)
Comments:  
The simultaneous monitoring [OH] and [CN] using cavity ring-down absorption measurements at ca. 790 nm (CN) and 2600 to 3300 nm (OH).

The error includes both statistical (one standard error) and systematic uncertainties.

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