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Author(s):   Dong, F.; Wang, S.; Kong, F.
Title:   Reaction of propargyl with oxygen
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   9374 - 9379
Year:   2003
Reference type:   Journal article
Squib:   2003DON/WAN9374-9379

Reaction:   CH2C≡CH + O2CO2 + C2H3
Reaction order:   2
Temperature:   298 K
Rate expression:   no rate data available
Bath gas:   Ar
Category:  Experiment
Data type:   Mechanistic information only
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   By end product analysis
Analytical technique:   Chemiluminescence
Comments:   1) Temperature not reported; 298 K is presumed.
2) Products were identified by time-resolved Fourier transform infrared spectroscopy of emissions between 1800-3600 cm-1.

3) Propargyl radical was produced by 248 nm photolysis of propargyl bromide and seems presumed to be the only photolysis product.

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