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Author(s):   Goumri, A.; Yuan, J.; Hommel, E.L.; Marshall, P.
Title:   Kinetic studies of the reactions of hydroxyl radicals with the methyl-substituted silanes SiHn(CH3)(4-n) (n=0 to 4) at room temperature
Journal:   Chem. Phys. Lett.
Volume:   375
Page(s):   149 - 156
Year:   2003
Reference type:   Journal article
Squib:   2003GOU/YUA149-156

Reaction:   CH3SiH3 + ·OH → Products
Reaction order:   2
Temperature:   295 K
Rate expression:   3.3x10-11 [±4.0x10-12 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence
The temperature was between T = 293 K and T = 298 K.
The total pressure is not reported.
Error bars are 95% confidence intervals from the fit comined with a 10% allowance for possible systematic errors.

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