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Accessibility information
Author(s):   Knyazev, V.D.
Title:   Isodesmic reactions for transition states: Reactions of Cl atoms with methane and halogenated methanes
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   11082 - 11091
Year:   2003
Reference type:   Journal article
Squib:   2003KNY11082-11091

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2003KNY11082-11091   CH4 + ·Cl·CH3 + HCl                      
    2003KNY11082-11091   CH3Cl + ·Cl·CH2Cl + HCl                      
    2003KNY11082-11091   CH2Cl2 + ·ClCHCl2 + HCl                      
    2003KNY11082-11091   CHCl3 + ·Cl·CCl3 + HCl                      
    2003KNY11082-11091   CH3F + ·Cl·CH2F + HCl                      
    2003KNY11082-11091   CH2F2 + ·Cl·CHF2 + HCl                      
    2003KNY11082-11091   CHF3 + ·Cl·CF3 + HCl                      
    2003KNY11082-11091   CH2FCl + ·ClHCl + ·CClFH                      
    2003KNY11082-11091   CHF2Cl + ·Cl·CClF2 + HCl                      
    2003KNY11082-11091   CHFCl2 + ·Cl·CCl2F + HCl                      
    2003KNY11082-11091   CH3Br + ·ClHCl + ·CH2Br                      
    2003KNY11082-11091   CH2Br2 + ·ClHCl + CHBr2                      
    2003KNY11082-11091   CHBr3 + ·ClCBr3 + HCl                      
    2003KNY11082-11091   CHBrF2 + ·ClHCl + CBrF2                      
    2003KNY11082-11091   CH2ClBr + ·ClHCl + ·CHBrCl                      
    2003KNY11082-11091   CHBrCl2 + ·ClHCl + BrCCl2                      
    2003KNY11082-11091   CHClBr2 + ·ClHCl + CClBr2                      

Search returned 17 records.