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Accessibility information
Author(s):   Knyazev, V.D.
Title:   Isodesmic reactions for transition states: Reactions of Cl atoms with methane and halogenated methanes
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   11082 - 11091
Year:   2003
Reference type:   Journal article
Squib:   2003KNY11082-11091

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2003KNY11082-11091   CH4 + ·Cl·CH3 + HCl                      
    2003KNY11082-11091   CH3Cl + ·Cl·CH2Cl + HCl                      
    2003KNY11082-11091   CH2Cl2 + ·ClCHCl2 + HCl                      
    2003KNY11082-11091   CHCl3 + ·Cl·CCl3 + HCl                      
    2003KNY11082-11091   CH3F + ·Cl·CH2F + HCl                      
    2003KNY11082-11091   CH2F2 + ·Cl·CHF2 + HCl                      
    2003KNY11082-11091   CHF3 + ·Cl·CF3 + HCl                      
    2003KNY11082-11091   CH2FCl + ·ClHCl + ·CClFH                      
    2003KNY11082-11091   CHF2Cl + ·Cl·CClF2 + HCl                      
    2003KNY11082-11091   CHFCl2 + ·Cl·CCl2F + HCl                      
    2003KNY11082-11091   CH3Br + ·ClHCl + ·CH2Br                      
    2003KNY11082-11091   CH2Br2 + ·ClHCl + CHBr2                      
    2003KNY11082-11091   CHBr3 + ·ClCBr3 + HCl                      
    2003KNY11082-11091   CHBrF2 + ·ClHCl + CBrF2                      
    2003KNY11082-11091   CH2ClBr + ·ClHCl + ·CHBrCl                      
    2003KNY11082-11091   CHBrCl2 + ·ClHCl + BrCCl2                      
    2003KNY11082-11091   CHClBr2 + ·ClHCl + CClBr2                      

Search returned 17 records.