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Author(s):   Lee, W.; Stevens, P.S.; Hites, R.A.
Title:   Rate Constants for the Gas-Phase Reactions of Methylphenanthrenes with OH as a Function of Temperature
Journal:   J. Phys. Chem. A
Volume:   107
Page(s):   6603 - 6608
Year:   2003
Reference type:   Journal article
Squib:   2003LEE/STE6603-6608

Reaction:   Phenanthrene-d10 + ·OH → Products
Reaction order:   2
Reference reaction:   Phenanthrene + ·OH → Products
Temperature:   323 - 358 K
Pressure:  1.01 bar
Rate expression:   3.38x10-12 [cm3/molecule s] e6194 [±2503 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Measured at four temperatures: 323 K, 343 K, 353 K, and 358 K.

The rate constant of the reference reaction, OH + Phenanthrene, determined in this paper
k(OH + Phenanthrene) = 6.46*10-12*exp(477/T) cm3molecule-1s-1 was used.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
323 3.39E-11
325 3.35E-11
350 2.84E-11
358 2.71E-11