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Accessibility information
Author(s):   Rauk, A.; Boyd, R.J.; Boyd, S.L.; Henry, D.J.; Radom, L.
Title:   Alkoxy radicals in the gaseous phase: beta-scission reactions and formation by radical addition to carbonyl compounds
Journal:   Can. J. Chem.
Volume:   81
Page(s):   431 - 442
Year:   2003
Reference type:   Journal article
Squib:   2003RAU/BOY431-442

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003RAU/BOY431-442   CH3CH2O +       5.50E13       1.01E05      1
  2003RAU/BOY431-442   CH3CH2CH3CHO +       2.46E13       8.76E04      1
  2003RAU/BOY431-442   n-C3H7OC2H5CHO +       1.70E13       8.58E04      1
  2003RAU/BOY431-442   i-C3H7OAcetone +       1.58E13       7.66E04      1
  2003RAU/BOY431-442   CH3CH2CH(CH3)O· → C2H5COCH3 +       1.51E13       7.56E04      1
  2003RAU/BOY431-442   CH2=CHCH2O → CH2=CHCHO +       1.10E13       7.72E04      1
  2003RAU/BOY431-442   CH2=CHCH(CH3)O → CH2=CHCOCH3 +       9.77E12       7.22E04      1
  2003RAU/BOY431-442   CH3CH2CH2O + ·CH3      3.98E13       7.04E04      1
  2003RAU/BOY431-442   i-C3H7OCH3CHO + ·CH3      9.12E13       6.01E04      1
  2003RAU/BOY431-442   CH3CH2CH(CH3)O· → C2H5CHO + ·CH3      1.78E13       6.23E04      1
  2003RAU/BOY431-442   (CH3)3CO· → Acetone + ·CH3      1.15E14       5.69E04      1
  2003RAU/BOY431-442   CH2=CHCH(CH3)O → CH2=CHCHO + ·CH3      2.69E13       5.07E04      1
  2003RAU/BOY431-442   i-C3H7OCH2O + ·C2H5      5.89E13       5.81E04      1
  2003RAU/BOY431-442   CH3CH2CH(CH3)O· → CH3CHO + ·C2H5      5.25E13       4.89E04      1
  2003RAU/BOY431-442   CH2=CHCH2O → CH2O + C2H3      3.39E14       9.48E04      1
  2003RAU/BOY431-442   CH2=CHCH(CH3)O → CH3CHO + C2H3      1.74E14       8.56E04      1
  2003RAU/BOY431-442   CH2O + CH3      3.89E-11       1.87E04      2
  2003RAU/BOY431-442   C2H5CHO + n-C3H7O      1.15E-11       2.62E04      2
  2003RAU/BOY431-442   Acetone + i-C3H7O      6.31E-12       3.50E04      2
  2003RAU/BOY431-442   CH3CHO + CH3CH2      1.62E-11       2.70E04      2
  2003RAU/BOY431-442   C2H5COCH3 + → CH3CH2CH(CH3)O·      9.55E-12       3.26E04      2
  2003RAU/BOY431-442   CH2=CHCOCH3 + → CH2=CHCH(CH3)O      3.67E-11       3.25E04      2
  2003RAU/BOY431-442   CH2=CHCHO + → CH2=CHCH2O      2.74E-11       2.74E04      2
  2003RAU/BOY431-442   CH2O + ·CH3CH3CH2      4.27E-13       2.51E04      2
  2003RAU/BOY431-442   CH3CHO + ·CH3i-C3H7O      1.07E-13       3.55E04      2
  2003RAU/BOY431-442   C2H5CHO + ·CH3 → CH3CH2CH(CH3)O·      5.63E-14       3.65E04      2
  2003RAU/BOY431-442   Acetone + ·CH3 → (CH3)3CO·      2.51E-14       4.30E04      2
  2003RAU/BOY431-442   CH2=CHCHO + ·CH3 → CH2=CHCH(CH3)O      5.15E-13       3.38E04      2
  2003RAU/BOY431-442   CH2O + ·C2H5n-C3H7O      5.50E-14       1.57E04      2
  2003RAU/BOY431-442   CH3CHO + ·C2H5 → CH3CH2CH(CH3)O·      1.41E-14       2.50E04      2
  2003RAU/BOY431-442   CH2O + C2H3 → CH2=CHCH2O      5.63E-13       1.04E04      2
  2003RAU/BOY431-442   CH3CHO + C2H3 → CH2=CHCH(CH3)O      1.55E-13       1.65E04      2

Search returned 32 records.