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Accessibility information
Author(s):   Swihart, M.T.; Catoire, L.; Legrand, B.; Gokalp, I.; Paillard, C.
Title:   Rate constants for the homogeneous gas-phase Al/HCl combustion chemistry
Journal:   Combust. Flame
Volume:   132
Page(s):   91 - 101
Year:   2003
Reference type:   Journal article
Squib:   2003SWI/CAT91-101

Reaction:   AlH3 + ClHCl + AlH2
Reaction order:   2
Temperature:   500 - 4000 K
Pressure:  50.66 bar
Rate expression:   7.89x10-15 [cm3/molecule s] (T/298 K)1.50
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Comments:   Estimates based on log A = 9.2 times number of abstractable atoms, T^1.5, and barrier of zero, rates to be used in modeling Al combustion reactions

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
500 1.71E-14
600 2.25E-14
700 2.84E-14
800 3.47E-14
900 4.14E-14
1000 4.85E-14
1100 5.59E-14
1200 6.37E-14
1300 7.19E-14
1400 8.03E-14
1500 8.91E-14
1600 9.81E-14
1700 1.07E-13
1800 1.17E-13
1900 1.27E-13
2000 1.37E-13
2100 1.48E-13
2200 1.58E-13
2300 1.69E-13
2400 1.80E-13
2500 1.92E-13
2600 2.03E-13
2700 2.15E-13
2800 2.27E-13
2900 2.39E-13
3000 2.52E-13
3100 2.65E-13
3200 2.78E-13
3300 2.91E-13
3400 3.04E-13
3500 3.17E-13
3600 3.31E-13
3700 3.45E-13
3800 3.59E-13
3900 3.73E-13
4000 3.88E-13