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Accessibility information
Author(s):   Urata, S.; Takada, A.; Uchimaru, T.; Chandra, A.K.
Title:   Rate constants estimation for the reaction of hydrofluorocarbons and hydrofluoroethers with OH radicals
Journal:   Chem. Phys. Lett.
Volume:   368
Page(s):   215 - 223
Year:   2003
Reference type:   Journal article
Squib:   2003URA/TAK215-223

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003URA/TAK215-223   CH3CF3 + ·OHCF3CH2 + H2O  298   3.20E-15           3.20E-15  2
  2003URA/TAK215-223   CH3CF3 + ·OHCF3CH2 + H2O  298   1.10E-15           1.10E-15  2
  2003URA/TAK215-223   CF3CH2F + ·OHH2O + CF3CHF  298   5.20E-15           5.20E-15  2
  2003URA/TAK215-223   CF3CH2F + ·OHH2O + CF3CHF  298   6.00E-15           6.00E-15  2
  2003URA/TAK215-223   C2F5H + ·OHC2F5 + H2O  298   2.10E-15           2.10E-15  2
  2003URA/TAK215-223   C2F5H + ·OHC2F5 + H2O  298   1.80E-15           1.80E-15  2
  2003URA/TAK215-223   CH3CHF2 + ·OH → Other Products + H2O  298   8.00E-15           8.00E-15  2
  2003URA/TAK215-223   CH3CHF2 + ·OH → Other Products + H2O  298   8.50E-15           8.50E-15  2
  2003URA/TAK215-223   CHF2CHF2 + ·OHH2O + CHF2CF2  298   4.80E-15           4.80E-15  2
  2003URA/TAK215-223   CHF2CHF2 + ·OHH2O + CHF2CF2  298   5.20E-15           5.20E-15  2
  2003URA/TAK215-223   CF3CHFCF3 + ·OH(CF3)2CF + H2O  298   3.00E-15           3.00E-15  2
  2003URA/TAK215-223   CF3CHFCF3 + ·OH(CF3)2CF + H2O  298   4.50E-15           4.50E-15  2
  2003URA/TAK215-223   CF3CH2CHF2 + ·OH → Other Products + H2O  298   8.00E-15           8.00E-15  2
  2003URA/TAK215-223   CF3CH2CHF2 + ·OH → Other Products + H2O  298   1.03E-14           1.03E-14  2
  2003URA/TAK215-223   CF3CH2CH2CF3 + ·OH → CF3CH2CH(·)CF3 + H2O  298   7.40E-15           7.40E-15  2
  2003URA/TAK215-223   CF3CH2CH2CF3 + ·OH → CF3CH2CH(·)CF3 + H2O  298   5.80E-15           5.80E-15  2
  2003URA/TAK215-223   CF3CH2CF2CH3 + ·OH → Other Products + H2O  298   6.20E-15           6.20E-15  2
  2003URA/TAK215-223   CF3CH2CF2CH3 + ·OH → Other Products + H2O  298   3.10E-15           3.10E-15  2
  2003URA/TAK215-223   (CH3)2O + ·OHH2O + CH3OCH2  298   2.73E-12           2.73E-12  2
  2003URA/TAK215-223   (CH3)2O + ·OHH2O + CH3OCH2  298   6.49E-13           6.49E-13  2
  2003URA/TAK215-223   CF3OCH3 + ·OH → CF3OCH2(.) + H2O  298   2.68E-14           2.68E-14  2
  2003URA/TAK215-223   CF3OCH3 + ·OH → CF3OCH2(.) + H2O  298   1.87E-14           1.87E-14  2
  2003URA/TAK215-223   CHF2-O-CHF2 + ·OH → CHF2OCF2· + H2O  298   1.00E-15           1.00E-15  2
  2003URA/TAK215-223   CHF2-O-CHF2 + ·OH → CHF2OCF2· + H2O  298   1.70E-15           1.70E-15  2
  2003URA/TAK215-223   ·OH + Pentafluorodimethyl etherH2O + CF3OCF2(·)  298   3.00E-16           3.00E-16  2
  2003URA/TAK215-223   ·OH + Pentafluorodimethyl etherH2O + CF3OCF2(·)  298   5.00E-16           5.00E-16  2
  2003URA/TAK215-223   CH3OCF2CHF2 + ·OH → Other Products + H2O  298   1.80E-14           1.80E-14  2
  2003URA/TAK215-223   CH3OCF2CHF2 + ·OH → Other Products + H2O  298   1.50E-14           1.50E-14  2
  2003URA/TAK215-223   CF3CH2OCHF2 + ·OH → Other Products + H2O  298   9.86E-14           9.86E-14  2
  2003URA/TAK215-223   CF3CH2OCHF2 + ·OH → Other Products + H2O  298   4.36E-14           4.36E-14  2
  2003URA/TAK215-223   CH3OCF2CF3 + ·OH → ·CH2OCF2CF3 + H2O  298   1.56E-14           1.56E-14  2
  2003URA/TAK215-223   CH3OCF2CF3 + ·OH → ·CH2OCF2CF3 + H2O  298   1.26E-14           1.26E-14  2
  2003URA/TAK215-223   CF3CHFCF2OCH3 + ·OH → Other Products + H2O  298   1.87E-14           1.87E-14  2
  2003URA/TAK215-223   CF3CHFCF2OCH3 + ·OH → Other Products + H2O  298   1.77E-14           1.77E-14  2
  2003URA/TAK215-223   CF3CH2OCH2CF3 + ·OH → CF3CH(.)OCH2CF3 + H2O  298   4.55E-13           4.55E-13  2
  2003URA/TAK215-223   CF3CH2OCH2CF3 + ·OH → CF3CH(.)OCH2CF3 + H2O  298   1.54E-13           1.54E-13  2
  2003URA/TAK215-223   CH3OCF2CF2CF3 + ·OH → CF3CF2CF2OCH2 + H2O  298   1.54E-14           1.54E-14  2
  2003URA/TAK215-223   CH3OCF2CF2CF3 + ·OH → CF3CF2CF2OCH2 + H2O  298   1.25E-14           1.25E-14  2
  2003URA/TAK215-223   CF3CH2OCF2CF2H + ·OH → Other Products + H2O  298   1.61E-14           1.61E-14  2
  2003URA/TAK215-223   CF3CH2OCF2CF2H + ·OH → Other Products + H2O  298   1.26E-14           1.26E-14  2
  2003URA/TAK215-223   CHF2OCH2CF2CF3 + ·OH → Other Products + H2O  298   1.74E-13           1.74E-13  2
  2003URA/TAK215-223   CHF2OCH2CF2CF3 + ·OH → Other Products + H2O  298   6.48E-14           6.48E-14  2
  2003URA/TAK215-223   CH3OCF(CF3)2 + ·OH → CF3CF2CF2OCH2 + H2O  298   5.40E-15           5.40E-15  2
  2003URA/TAK215-223   CH3OCF(CF3)2 + ·OH → CF3CF2CF2OCH2 + H2O  298   5.90E-15           5.90E-15  2
  2003URA/TAK215-223   C2H5F + ·OH → Other Products + H2O  298   1.83E-14           1.83E-14  2
  2003URA/TAK215-223   C2H5F + ·OH → Other Products + H2O  298   4.28E-14           4.28E-14  2
  2003URA/TAK215-223   CH2FCHF2 + ·OH → Other Products + H2O  298   9.50E-15           9.50E-15  2
  2003URA/TAK215-223   CH2FCHF2 + ·OH → Other Products + H2O  298   1.40E-14           1.40E-14  2
  2003URA/TAK215-223   CH3CH2CF3 + ·OH → Other Products + H2O  298   1.38E-14           1.38E-14  2
  2003URA/TAK215-223   CH3CH2CF3 + ·OH → Other Products + H2O  298   3.21E-14           3.21E-14  2
  2003URA/TAK215-223   Propane, 1,1,2,2,3-pentafluoro- + ·OH → Other Products + H2O  298   6.70E-15           6.70E-15  2
  2003URA/TAK215-223   Propane, 1,1,2,2,3-pentafluoro- + ·OH → Other Products + H2O  298   6.50E-15           6.50E-15  2
  2003URA/TAK215-223   CF3CHFCH2F + ·OH → Other Products + H2O  298   1.01E-14           1.01E-14  2
  2003URA/TAK215-223   CF3CHFCH2F + ·OH → Other Products + H2O  298   2.02E-14           2.02E-14  2
  2003URA/TAK215-223   ·OH + CHF2CHFCHF2 → Other Products + H2O  298   1.02E-14           1.02E-14  2
  2003URA/TAK215-223   ·OH + CHF2CHFCHF2 → Other Products + H2O  298   2.05E-14           2.05E-14  2
  2003URA/TAK215-223   Propane, 1,1,1,2,2,3-hexafluoro- + ·OH → CF3CF2CHF· + H2O  298   4.00E-15           4.00E-15  2
  2003URA/TAK215-223   Propane, 1,1,1,2,2,3-hexafluoro- + ·OH → CF3CF2CHF· + H2O  298   3.30E-15           3.30E-15  2
  2003URA/TAK215-223   1,1,1,2,3,3-Hexafluoropropane + ·OH → Other Products + H2O  298   6.40E-15           6.40E-15  2
  2003URA/TAK215-223   1,1,1,2,3,3-Hexafluoropropane + ·OH → Other Products + H2O  298   1.07E-14           1.07E-14  2
  2003URA/TAK215-223   Propane, 1,1,1,3,3,3-hexafluoro- + ·OHH2O + (CF3)2CH·  298   3.60E-15           3.60E-15  2
  2003URA/TAK215-223   Propane, 1,1,1,3,3,3-hexafluoro- + ·OHH2O + (CF3)2CH·  298   2.60E-15           2.60E-15  2
  2003URA/TAK215-223   ·OH + CF3CF2CH2CH2F → Other Products + H2O  298   1.13E-14           1.13E-14  2
  2003URA/TAK215-223   ·OH + CF3CF2CH2CH2F → Other Products + H2O  298   1.82E-14           1.82E-14  2
  2003URA/TAK215-223   CHF2CF2CF2CHF2 + ·OH → CHF2CF2CF2CF2· + H2O  298   4.40E-15           4.40E-15  2
  2003URA/TAK215-223   CHF2CF2CF2CHF2 + ·OH → CHF2CF2CF2CF2· + H2O  298   4.30E-15           4.30E-15  2
  2003URA/TAK215-223   ·OH + CF3CH2CF2CH2CF3 → CF3CH2CF2CH(.)CF3 + H2O  298   7.00E-15           7.00E-15  2
  2003URA/TAK215-223   ·OH + CF3CH2CF2CH2CF3 → CF3CH2CF2CH(.)CF3 + H2O  298   4.90E-15           4.90E-15  2
  2003URA/TAK215-223   ·OH + CF3CHFCHFCF2CF3 → Other Products + H2O  298   6.30E-15           6.30E-15  2
  2003URA/TAK215-223   ·OH + CF3CHFCHFCF2CF3 → Other Products + H2O  298   1.06E-14           1.06E-14  2
  2003URA/TAK215-223   ·OH + CF3CF2CH2CH2CF2CF3 → CF3CF2CH2CH(.)CF2CF3 + H2O  298   5.60E-15           5.60E-15  2
  2003URA/TAK215-223   ·OH + CF3CF2CH2CH2CF2CF3 → CF3CF2CH2CH(.)CF2CF3 + H2O  298   3.00E-15           3.00E-15  2
  2003URA/TAK215-223   CF3CH2OCH3 + ·OH → Other Products + H2O  298   1.27E-12           1.27E-12  2
  2003URA/TAK215-223   CF3CH2OCH3 + ·OH → Other Products + H2O  298   3.25E-13           3.25E-13  2
  2003URA/TAK215-223   CH3CH2OCF2CF2H + ·OH → Other Products + H2O  298   1.72E-13           1.72E-13  2
  2003URA/TAK215-223   CH3CH2OCF2CF2H + ·OH → Other Products + H2O  298   6.69E-14           6.69E-14  2
  2003URA/TAK215-223   CHF2OCH2CF2CHF2 + ·OH → Other Products + H2O  298   1.70E-13           1.70E-13  2
  2003URA/TAK215-223   CHF2OCH2CF2CHF2 + ·OH → Other Products + H2O  298   6.62E-14           6.62E-14  2
  2003URA/TAK215-223   CF3CHFCF2OCH2CF3 + ·OH → CH2OC4F9 + H2O  298   1.53E-14           1.53E-14  2
  2003URA/TAK215-223   CF3CHFCF2OCH2CF3 + ·OH → CH2OC4F9 + H2O  298   1.24E-14           1.24E-14  2
  2003URA/TAK215-223   CF3CF2CF2CF2OCH2CH3 + ·OH → Other Products + H2O  298   1.66E-13           1.66E-13  2
  2003URA/TAK215-223   CF3CF2CF2CF2OCH2CH3 + ·OH → Other Products + H2O  298   6.31E-14           6.31E-14  2
  2003URA/TAK215-223   CF3CF2CF2CF2OCH2CH3 + ·OH → Other Products + H2O  298   6.31E-14           6.31E-14  2
  2003URA/TAK215-223   CF3CF2CF2CF2OCH2CH3 + ·OH → Other Products + H2O  298   1.66E-13           1.66E-13  2
  2003URA/TAK215-223   ·OH + HCF2OCF2CF2OCF2H → CHF2OCF2CF2OCF2 + H2O  298   8.00E-16           8.00E-16  2
  2003URA/TAK215-223   ·OH + HCF2OCF2CF2OCF2H → CHF2OCF2CF2OCF2 + H2O  298   1.40E-15           1.40E-15  2
  2003URA/TAK215-223   CH2FCH2OH + ·OH → Other Products + H2O  298   1.92E-13           1.92E-13  2
  2003URA/TAK215-223   CH3OCHF2 + ·OH → Other Products + H2O  298   5.96E-14           5.96E-14  2
  2003URA/TAK215-223   CHF2CH2OCF3 + ·OH → Other Products + H2O  298   3.27E-14           3.27E-14  2
  2003URA/TAK215-223   CH2FCF2OCHF2 + ·OH → Other Products + H2O  298   6.50E-15           6.50E-15  2
  2003URA/TAK215-223   CF3CH(OH)CF3 + ·OH → CF3CHOCF3 + H2O  298   1.49E-14           1.49E-14  2
  2003URA/TAK215-223   CF3CH(OH)CF3 + ·OH → Other Products + H2O  298   3.00E-15           3.00E-15  2
  2003URA/TAK215-223   1,2,2,2-tetrafluoroethyl trifluoromethyl ether + ·OHH2O + CF3OCF2CF2·  298   2.30E-15           2.30E-15  2
  2003URA/TAK215-223   1,2,2,2-tetrafluoroethyl trifluoromethyl ether + ·OH → CF3CF(.)OCF3 + H2O  298   1.30E-15           1.30E-15  2
  2003URA/TAK215-223   CHF2CF2CH2OCH3 + ·OH → Other Products + H2O  298   3.92E-13           3.92E-13  2
  2003URA/TAK215-223   CF3CF2CH2OCH3 + ·OH → Other Products + H2O  298   3.93E-13           3.93E-13  2
  2003URA/TAK215-223   CHF2CF2CF2OCH3 + ·OH → Other Products + H2O  298   1.55E-14           1.55E-14  2
  2003URA/TAK215-223   CF3CF2CH2OCF3 + ·OH → CF3CF2CH(.)OCF3 + H2O  298   2.36E-14           2.36E-14  2
  2003URA/TAK215-223   CF3CF2CH2OCF3 + ·OH → CF3CF2CH(.)OCF3 + H2O  298   1.03E-14           1.03E-14  2
  2003URA/TAK215-223   CHF2CF2CH2OCF2CHF2 + ·OH → Other Products + H2O  298   2.12E-14           2.12E-14  2
  2003URA/TAK215-223   CHF2CF2CH2OCF2CHF2 + ·OH → Other Products + H2O  298   6.82E-14           6.82E-14  2
  2003URA/TAK215-223   CHF2CF2CH2OCF2CHF2 + ·OH → Other Products + H2O  298   1.53E-14           1.53E-14  2
  2003URA/TAK215-223   CF3CHFCF2OCH2CF3 + ·OH → Other Products + H2O  298   1.54E-14           1.54E-14  2
  2003URA/TAK215-223   CF3CHFCF2OCH2CF3 + ·OH → Other Products + H2O  298   1.87E-14           1.87E-14  2
  2003URA/TAK215-223   CHF2CF2CF2CF2CH2OCH3 + ·OH → Other Products + H2O  298   3.83E-13           3.83E-13  2
  2003URA/TAK215-223   ·OH + CF3CHFCF2OCH2CF2CHF2 → Other Products + H2O  298   2.40E-14           2.40E-14  2

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