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Author(s):   Andersen, M.PS.; Hurley, M.D.; Wallington, T.J.; Blandini, F.; Jensen, N.R.; Librando, V.; Hjorth, J.; Marchionni, G.; Avataneo, M.; Visca, M.; Nicolaisen, F.M.; Nielsen, O.J.
Title:   Atmospheric chemistry of CH3O(CF2CF2O)nCH3 (n=1-3): Kinetics and mechanism of oxidation initiated by Cl atoms and OH radicals, IR spectra, and global warming potentials
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   1964 - 1972
Year:   2004
Reference type:   Journal article
Squib:   2004AND/HUR1964-1972

Reaction:   CH3O(CF2CF2O)3CH3 + Cl → CH3OCF2CF2OCH2 + HCl
Reaction order:   2
Reference reaction:   CH3Cl + Cl → Products
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   3.95x10-13 [±4.0x10-14 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)

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