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Author(s):   Becerra, R.; Goldberg, N.; Cannady, J.P.; Almond, M.J.; Ogden, J.S.; Walsh, R.
Title:   Experimental and theoretical evidence for homogeneous catalysis in the gas-phase reaction of SiH2 with H2O (and D2O): A combined kinetic and quantum chemical study
Journal:   J. Am. Chem. Soc.
Volume:   126
Page(s):   6816 - 6824
Year:   2004
Reference type:   Journal article
Squib:   2004BEC/GOL6816-6824

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2004BEC/GOL6816-6824   H2O + H2O + SiH2H2O + SiH3OH  297   3.80E-51              3
  2004BEC/GOL6816-6824   H2O + H2O + SiH2H2O + SiH3OH  345   6.80E-31              3
  2004BEC/GOL6816-6824   D2O + D2O + SiH2 → SiH2DOD + D2O  297   2.18E-30              3
  2004BEC/GOL6816-6824   D2O + D2O + SiH2 → SiH2DOD + D2O  345   5.40E-31              3
  2004BEC/GOL6816-6824   H2O + H2O + SiH2H2O + SiH3OH  297   6.00E-30              3
  2004BEC/GOL6816-6824   H2O + H2O + SiH2H2O + SiH3OH  345   2.95E-30              3
  2004BEC/GOL6816-6824   D2O + D2O + SiH2 → SiH2DOD + D2O  297   5.40E-30              3
  2004BEC/GOL6816-6824   D2O + D2O + SiH2 → SiH2DOD + D2O  345   2.20E-30              3

Search returned 8 records.