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Author(s):   Chuchani, G.; Tosta, M.; Rotinov, A.; Herize, A.
Title:   Kinetics and mechanisms of elimination of ethyl 3-phenyl and ethyl 3-methyl-3-phenyl glycidates in the gas phase
Journal:   J. Phys. Org. Chem.
Volume:   17
Page(s):   694 - 698
Year:   2004
Reference type:   Journal article
Squib:   2004CHU/TOS694-698

Reaction:   ethyl 3-phenyl glycidate → C2H4 + Phenylethanal + CO2
Reaction order:   1
Temperature:   623 - 673 K
Pressure:  4.27E-2 - 0.30 bar
Rate expression:   1.41x1012 [s-1] e-190100 [±5800 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Pressure measurement
Comments:   Reaction products were verified by GC-MS analysis.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
623 1.66E-4
625 1.83E-4
650 7.46E-4
673 2.46E-3