Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Hasson, A.S.; Tyndall, G.S.; Orlando, J.J.
Title:   A product yield study of the reaction of HO2 radicals with ethyl peroxy (C2H5O2), acetyl peroxy (CH3C(O)O2), and acetonyl peroxy (CH3C(O)CH2O2) radicals
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   5979 - 5989
Year:   2004
Reference type:   Journal article
Squib:   2004HAS/TYN5979-5989

Reaction:   HO2 + CH3C(O)CH2OO· → CH3C(O)CH2O· + ·OH + O2
Reaction order:   2
Reference reaction:   HO2 + CH3C(O)CH2OO· → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.07 bar
Rate expression:   6.7x10-1±2.0x10-1
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.